Three types of zircon coexist in an unusual lower crustal xenolith from the Valle Guffari diatreme (Hyblean Plateau, Sicily): igneous Type 1 (near-euhedral, weakly zoned; Ce/Ce > 1); partially recrystallised Type 2 (ovoid, structureless; weak Ce anomaly); hydrothermal Type 3 (sugary, spongy-textured, probably related to F-rich aqueous fluids). U–Pb dating by LAM-ICPMS, supported by in situ Hf-isotope analysis, suggests that both Type 1 and Type 2 zircons were originally Archean (ca 2.7 Ga), though many of these grains have experienced severe Pb loss. The U–Pb ages of the hydrothermal zircons cluster around 246 Ma, interpreted as the timing of the hydrothermal event. Their εHf (+ 8.5 to − 1.2) indicates the mixing of old crustal components and material from a juvenile source.
In situ Os-isotope analyses of sulfides hosted in peridotite xenoliths from Valle Guffari show Paleoproterozoic–Archean TRDminimum ages, corresponding to the age of the oldest zircon grains in the crustal xenolith. Other peaks of TRD ages suggest that multiple metasomatic events have affected the lithospheric mantle.
These observations suggest that the lower crust and the upper part of the lithospheric mantle beneath the Hyblean Plateau represent the northernmost portion of the African Plate. These two units have coexisted since at least late Archean time, and have remained linked through several episodes of crustal modification, including the Permo-Triassic hydrothermal event, which was probably related to the onset of rifting in the Ionian Basin. 相似文献
Extended X-ray absorption fine structure (EXAFS) spectroscopy and chemical analyses were combined to determine the Fe bearing minerals in recent lake sediments from Baldeggersee (Switzerland). The upper section of a laminated sediment core, deposited under eutrophic conditions, was compared to the lower part from an oligotrophic period. Qualitative analysis of FeK EXAFS agreed well with chemical data: In the oligotrophic section Fe(II)–O and Fe(III)–O specieswere present, whereas a significant fraction of Fe(II)–S sulfides was strongly indicated in the eutrophic part. A statistical analysis was performed by least square fitting of normalized reference spectra. The set of reference minerals included Fe(III) oxides and Fe(II) sulfides, carbonates and phosphates. In the oligotrophic regime no satisfying fit was obtained using the set of reference spectra, indicating that siderite (FeCO3) was not present in a significant amount in these carbonate-rich sediments. Simulated EXAFS spectra for a(Cax, Fe1-x)CO3solid solution allowed reconstructing the specificfeatures of the experimental spectra, suggesting that this phase was the dominant Fe carrier in the oligotrophic section of the core. In the eutrophic part, mackinawite was positively identified and represented the dominant Fe(II) sulfide phase. This finding agreed with chemical extraction, which indicated that18–40 mol% of Fe was contained in the acid volatile iron sulfide fraction. EXAFS spectra of the eutrophic section were best fitted by considering the admixture of mackinawite and the Fe–Ca carbonate phase inferred to be predominant in the oligotrophic regime. 相似文献
Abstract. The Liwu Cu‐rich sulfide deposit occurs within the Jianglang dome in the eastern margin of the Tibetan plateau. The dome consists of a core, a middle slab and a cover sequence. The main deposit is hosted in the core with minor ore bodies in the middle slab. The protolith of the core consists of clastic sedimentary rocks with inter‐layered volcanic rocks. All of the ore bodies are substantially controlled by an extensional detachment fault system. The ore bodies within the core are distributed along the S2 foliation in the hinge of recumbent fold (D2), whereas ore bodies with en echelon arrangement are controlled by the mylonitic foliation of the lower detachment fault. Ore bodies within the middle slab are oriented with their axes parallel to the mylonitic foliation. Pyrite and pyrrhotite from the ores contain Co ranging from 37 to 1985 ppm, Ni from 2.5 to 28.1 ppm, and Co/Ni ratios from 5 to 71. These sulfides have δ34S values ranging from 1.5 to 7.5 % whereas quartz separates have δ18O values of 11.9 and 14.3 % and inclusion fluid in quartz has δD value of‐88.1 %. These features suggest that the deposit was of hydrothermal origin. Two ore‐forming stages are recognized in the evolution of the Jianglang dome. (1) A low‐temperature ore‐forming process, during the tectonic transport of the upper plate above the lower detachment, and the initial phase of the footwall updom‐ing at 192–177 Ma. (2) A medium‐temperature ore‐forming stage, related to the final structural development of the initial detachment at 131–81Ma. Within the core, the ore bodies of the first stage were uplifted to, or near, the brittle/ductile horizon where the ore‐forming metals were re‐concentrated and enriched. A denudation stage in which a compressional tectonic event produced eastward thrusting overprinted the previous structures, and finally denuded the deposit. The Liwu Cu‐rich sulfide deposit was formed during a regional extensional tectonic event and is defined as a tectono‐strata‐bound hydrothermal ore deposit. 相似文献
The magmatic processes leading to porphyry-Cu mineralizationat Santa Rita are reconstructed on the basis of petrographicstudies, thermobarometry, and laser-ablation inductively-coupled-plasmamass-spectrometry analyses of silicate melt and sulfide inclusionsfrom dikes ranging from basaltic andesite to rhyodacite. Combinedresults suggest that magma evolution at Santa Rita is similarto that of sulfur-rich volcanoes situated above subduction zones,being characterized by repeated injection of hot, mafic magmainto an anhydrite-bearing magma chamber of rhyodacitic composition.The most mafic end-member identified at Santa Rita is a shoshoniticbasaltic andesite that crystallized at 10001050°C,13 kbar and log fO2 = NNO + 0·7 to NNO + 1·0,whereas the rhyodacite crystallized at 730760°C andlog fO2 = NNO + 1·3 to NNO + 1·9. Mixing betweenthe two magmas caused precipitation of 0·10·2wt % magmatic sulfides and an associated decrease in the Cucontent of the silicate melt from 300500 ppm to lessthan 20 ppm. Quantitative modeling suggests that temporal storageof ore-metals in magmatic sulfides does not significantly enhancethe amount of copper ultimately available to ore-forming hydrothermalfluids. Magmatic sulfides are therefore not vital to the formationof porphyry-Cu deposits, unless a mechanism is required thatholds back ore-forming metals until late in the evolution ofthe volcanicplutonic system. KEY WORDS: porphyry-Cu; sulfur; sulfides; magma mixing; LA-ICP-MS相似文献